Hi there! Lemme throw some peeps at you!!!@ANGELA DEL TORO
& Doctor Doom
Doom might not give Angela too much notice outside of her superhero identity. He might, however, take some interest in her pendants as a mystical artifact for study and, eventually, acquisition (not that she'd let him take them, obviously). It'd make a very interesting conflict between the two at some point.
Angela & Wade
Angela would be hit on and would likely get to stab Wade a few times. Or, Angela would be hit on and she and Wade might have one of the few weird friendships he has. Lot of ways it could potentially go.
Angela & Sif
Badass warrior team up? Sif is no stranger to magic, so she wouldn't find the White Tiger stuff to be all that odd. They might make a good team at some point.
Angela & Rick
Rick Jones, professional sidekick. His superpower is being a sidekick! Also, he runs the Brigade, a clandestine group of people who seek to aid superhumans who aren't actively trying to cause harm to others in escaping the Sokovia Accords.
Given Angela's dislike of vigilantes, I think she and Rick might end up conflicting a bit...even if Rick's status and the Brigade aren't public. Could be some fun, maybe?
Unless, of course, Angela falls on the opposing side of the Sokovia Accords, which would change the dynamic somewhat.
Also, Rick being faced with an overly attractive woman who makes him hilariously awkward would be really funny, because he's a bit of a complete dork
. And keep in mind, he did actually survive Natasha. xD
Also, once Angela goes vigilante, there might be a plot with Rick and others that you might be interested in with her. Could be lots of fun and could get her some networking in!